Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS     

Kaj Sullivan  Daniel Layton‐Matthews  Matthew Leybourne  James Kidder  Zoltn Mester  Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.  相似文献   

Middle Permian organic carbon isotope stratigraphy and the origin of the Kamura Event     

《Gondwana Research》2020

Large carbon cycle perturbations associated with the Middle Permian (Capitanian) mass extinction have been widely reported, but their causes and timing are still in dispute. Low resolution carbon isotope records prior to this event also limit the construction of a Middle Permian chemostratigraphic framework and global or local stratigraphic correlation, and hence limit our understanding of carbon cycle and environmental changes. To investigate these issues, we analyzed the ¹³C_org values from the Middle Permian chert-mudstone sequence (Gufeng Formation) in the Lower Yangtze deep-water basin (South China) and compared them with published records to build a chemostratigraphic scheme and discuss the underlying environmental events. The records show increased δ¹³C_org values from late Kungurian to early Guadalupian, followed by a decrease to the late Wordian/early Capitanian. The early-mid Capitanian was characterized by elevated δ¹³C_org values suggesting the presence of the “Kamura Event”: an interval of heavy positive values seen in the δ¹³C_carb record. We propose that these heavy Capitanian δ¹³C values may be a response to a marked decline in chemical weathering rates on Pangea and associated reduction in carbonate burial, which we show using a biogeochemical model. The subsequent negative δ¹³C excursion seen in some carbonate records, especially in shallower-water sections (and in a muted expression in organic carbon) coincide with the Capitanian mass extinction may be caused by the input of isotopically-light carbon sourced from the terrestrial decomposition of organic matter.  相似文献   

Wave energy conversion under constrained wave-by-wave impedance matching with amplitude and phase-match limits     

《Applied Ocean Research》2019

This paper investigates an approach to limit the fullness of ‘tuning’ provided by wave-by-wave impedance matching control of wave energy devices in irregular waves. A single analytical formulation based on the Lagrange multiplier approach of Evans [1] is used to limit the velocity amplitude while also limiting the closeness of the phase match between velocity and exciting force. The paper studies the effect of the present technique in concurrently limiting the device velocity and the required control/actuation force. Time domain application requires wave-profile prediction, which here is based on a deterministic propagation model. Also examined in the time domain is the effect of possible violation of the displacement constraint, which for many designs implies impacts at hard stops within the power take-off mechanism. Time domain simulations are carried out for a 2-body axisymmetric converter (with physical end-stops) in sea states reported for a site off the US east coast. It is found that the approach leads to effective power conversion in the less energetic sea states, while as desired, considerable muting of the optimal response is found in the larger sea states. Under the assumptions of this work, the end-stop collisions are found to have a minor effect on the power conversion. The present approach could be used to guide the design of power take-off systems so that their displacement stroke, maximum force, and resistive and reactive power limits are well-matched to the achievable performance of a given controlled primary energy converter.  相似文献   

Wave tank and bench-top control testing of a wave energy converter     

《Applied Ocean Research》2019

An increasing number of experiments are being conducted to study the design and performance of wave energy converters. Often in these tests, a real-time realization of prospective control algorithms is applied in order to assess and optimize energy absorption as well as other factors. This paper details the design and execution of an experiment for evaluating the capability of a model-scale WEC to execute basic control algorithms. Model-scale hardware, system, and experimental design are considered, with a focus on providing an experimental setup capable of meeting the dynamic requirements of a control system. To more efficiently execute such tests, a dry bench testing method is proposed and utilized to allow for controller tuning and to give an initial assessment of controller performance; this is followed by wave tank testing. The trends from the dry bench test and wave tank test results show good agreement with theory and confirm the ability of a relatively simple feedback controller to substantially improve energy absorption. Additionally, the dry bench testing approach is shown to be an effective and efficient means of designing and testing both controllers and actuator systems for wave energy converters.  相似文献   

海洋气团对沿海城市大气环境影响与识别研究     

石红旗  王霄曈  张昊阳  石博欣  张睿 《海洋科学》2018,42(12):100-108

本研究通过识别海洋气团特征及沿海城市大气受到海洋气团的影响方式与程度,为评价沿海城市空气环境质量提供科学依据。以青岛市为例,收集大气气溶胶样品中放射性核素~(210)Pb、40K数据及采集时段当地大气颗粒物数据;分析~(210)Pb活度浓度与气溶胶颗粒物浓度变化;对当地当时大气气团进行溯源分析。研究表明:(1)研究期间青岛沿岸地区2015年4月至2016年6月与2016年6月至2017年6月大气污染特征显著不同,前者~(210)Pb活度浓度与污染颗粒物浓度显著相关,而后者~(210)Pb活度浓度与污染颗粒物无相关关系;(2)穿越海洋的陆地气团呈现出高活度浓度、低颗粒物浓度的特征;来自海洋气团的气溶胶呈现出低活度浓度、低颗粒物浓度的特征;(3)海洋气团气溶胶中~(210)Pb活度浓度较低。临近大陆的海洋(黄海、东海)上层大气受到大陆气团的影响,其海洋气团的特征有所减弱。~(210)Pb活度浓度、颗粒物浓度(PM2.5)可作为判断海洋气团的指标,识别"来自海洋的气团"与"经过海洋的气团"。  相似文献   

基于SODA资料的南海表层风能输入的空间分布与长期趋势研究     

杨倩  崔超然  张宇  刘志宇  管玉平  黄瑞新 《热带海洋学报》2018,37(6):41-48

海面风不仅是驱动上层海洋运动的主要动力, 其能量也是维持海洋表层流动的主要机械能来源。为了分析南海表层流风能输入的变化, 用SODA(Simple Ocean Data Assimilation)(1901—2010)资料估算了风向南海表层流(表层地转流+表层非地转流)的能量输入。结果表明, 风向南海表层流、表层地转流和表层非地转流输入的能量总体均呈减少趋势, 110年间分别减小了约56%、65%和49%。导致风能输入减小的最主要因素是风应力的减弱(减小了35%)。由于南海受季风系统的控制, 风向表层流及其各成分输入的能量呈现出显著的季节性变化。冬季风能输入最强, 高值区位于南海西部及北部区域, 呈一个显著的“回力镖”状结构。这些结果对深入认识南海环流具有理论意义。  相似文献   

The bivalve Lembulus bicuspidatus may enhance denitrification in shelf sediment at the Angola–Benguela Frontal Zone     

A Neumann  A Flohr 《African Journal of Marine Science》2018,40(1):91-96

We collected living individuals of the bivalve Lembulus bicuspidatus, which shows an unusual preference for the oxygen-deficient habitat found at the Angola–Benguela Frontal Zone of the southeastern Atlantic. With a series of incubation experiments with ¹⁵N-labelled nitrate as a tracer in combination with membrane-inlet mass spectrometry, we studied the potential contribution of L. bicuspidatus to nitrate reduction in the upper sediment layer. Our preliminary results suggest that L. bicuspidatus enhances nitrate reduction if the oxygen concentration is sufficiently low. The Lembulus-mediated nitrate reduction rate is then similar to the rate of microbial nitrate reduction in the surrounding sediment.  相似文献   

1970-2016年青藏高原岗扎日冰川变化与物质平衡遥感监测研究     

张震  刘时银 《地球信息科学学报》2018,20(9):1338-1349

可可西里处于青藏高原腹地,是青藏高原自然环境的交接与过渡地带。近年来该区域冰川物质平衡可能有从西向东由正转负的趋势,但是其过渡地带岗扎日地区冰川状态未知。本研究利用地形图、SRTM、ASTER和Landsat等资料分析了岗扎日地区冰川面积变化和物质平衡变化,并对可可西里地区冰川变化空间规律进行了探讨,结果表明：①1970-2016年岗扎日冰川总面积年均缩小率为0.08±0.02%。2006年后冰川退缩趋势减缓。②1970-2012年岗扎日冰川平均减薄-8.64±0.30 m,体积减少1.45±0.06 km³,平均物质平衡为-0.21±0.01 m w.e. a^-1。冰川物质平衡趋势由负转正（1970-1999年：-0.34±0.01 m w.e. a^-1;1999-2012：0.16±0.02 w.e. a^-1）。③东南、南、西南朝向作为迎风坡,1970年以来其冰川物质亏损较小,1999-2012年呈现强烈的正平衡。冰川面积变化滞后于物质平衡变化,东朝向和东南朝向冰川面积缩小率最大,主要是因为冰川冰舌较长,末端所处的海拔较低。④气温升高是岗扎日冰川1970-1999年呈现负物质平衡状态的主因,降水增多是1999-2012年正平衡状态的主因。⑤可可西里地区冰川1970s以来面积年均缩小率从西向东不断增大、物质平衡下降,与西风环流和季风环流相关,但局地气候也影响冰川变化和物质平衡。  相似文献   

Near‐surface hydraulic conductivity of northern hemisphere glaciers          下载免费PDF全文

Ian T. Stevens  Tristram D.L. Irvine‐Fynn  Philip R. Porter  Joseph M. Cook  Arwyn Edwards  Martin Smart  Brian J. Moorman  Andy J. Hodson  Andrew C. Mitchell 《水文研究》2018,32(7):850-865

The hydrology of near‐surface glacier ice remains a neglected aspect of glacier hydrology despite its role in modulating meltwater delivery to downstream environments. To elucidate the hydrological characteristics of this near‐surface glacial weathering crust, we describe the design and operation of a capacitance‐based piezometer that enables rapid, economical deployment across multiple sites and provides an accurate, high‐resolution record of near‐surface water‐level fluctuations. Piezometers were employed at 10 northern hemisphere glaciers, and through the application of standard bail–recharge techniques, we derive hydraulic conductivity (K) values from 0.003 to 3.519 m day^?1, with a mean of 0.185 ± 0.019 m day^?1. These results are comparable to those obtained in other discrete studies of glacier near‐surface ice, and for firn, and indicate that the weathering crust represents a hydrologically inefficient aquifer. Hydraulic conductivity correlated positively with water table height but negatively with altitude and cumulative short‐wave radiation since the last synoptic period of either negative air temperatures or turbulent energy flux dominance. The large range of K observed suggests complex interactions between meteorological influences and differences arising from variability in ice structure and crystallography. Our data demonstrate a greater complexity of near‐surface ice hydrology than hitherto appreciated and support the notion that the weathering crust can regulate the supraglacial discharge response to melt production. The conductivities reported here, coupled with typical supraglacial channel spacing, suggest that meltwater can be retained within the weathering crust for at least several days. Not only does this have implications for the accuracy of predictive meltwater run‐off models, but we also argue for biogeochemical processes and transfers that are strongly conditioned by water residence time and the efficacy of the cascade of sediments, impurities, microbes, and nutrients to downstream ecosystems. Because continued atmospheric warming will incur rising snowline elevations and glacier thinning, the supraglacial hydrological system may assume greater importance in many mountainous regions, and consequently, detailing weathering crust hydraulics represents a research priority because the flow path it represents remains poorly constrained.  相似文献   

部分预制型钢混凝土梁抗震性能试验研究          下载免费PDF全文

郭敬超  邵永健  梁松  薛祯钰 《世界地震工程》2018,34(4):016-23

为探究部分预制型钢混凝土梁的抗震性能，进行了7个部分预制型钢混凝土梁试件的拟静力试验，研究了试件的裂缝开展过程、破坏形态、承载能力、延性、耗能能力和刚度退化情况，探究预制截面模式、剪跨比和后浇混凝土强度等对其抗震能力的影响。结果表明:地震作用下，该7个试件力学性能较好，剪跨比是影响试件抗震性能的首要要素，剪跨比大的试件耗能能力强，型钢约束部分混凝土可以提高试件的耗能能力，截面模式和后浇混凝土强度对抗震性能影响不大。  相似文献